LOCAL STUDY ON PERFLUORINATED MATERIALS AND THEIR PRESENCE IN SOME FOODS IN BAGHDAD GOVERNORATE
DOI:
https://doi.org/10.36103/r3kqhs49Keywords:
Chemical composition, Liquid chromatography followed by mass spectrometryAbstract
The objective of this study is to identify and quantify perfluorinated substances in different ready-to-eat foods found in the local markets of Baghdad Governorate. The emphasis is placed on these substances due to their extensive use in paper and cardboard packaging materials and the consequential health effects. The analysis utilized liquid chromatography coupled with mass spectrometric detection equipped with electrospray ionization. The values recorded for perfluorinated materials in samples of crispy chicken and french fries were (2.41 and 4.94) micrograms, respectively. As for samples of kebab, pizza, and cake, they were (5.14, 5.80 and 7.32) micrograms, respectively, and samples taken from stored ice cream (15-30–45) days recorded (0.23, 0.42 and 2.26) micrograms, respectively. It was found that the percentage of fat and the amount of perfluorinated substances in foods are directly related, and this is clearly evident from the fact that it was not detected in the French Bread samples, and may be due to the low percentage of fat which amounted to 0.86%., compared to the samples that showed positive results.
Received date: 22/10/2023
Accepted date: 14/1/2024
Published date: 26/1/2026
References
1- A.O.A.C. 2005. Association of Official Analytical Chemist. Official Methods of Analysis. USA.
2- AbulFadl, M.M.; A.M. Sharaf; M.M. Mostafa and M.H. El-Saeid, 2019.Impact of household cooking on release of fluorinated compounds pfoa and pfos from tefal coated cookware to foods. World J. Adv. Res. Rev., 3, 024–030. doi: 10.30574/wjarr.2019.3.2.0060.
3- Al khafaji M. 2023. Awareness of iraqi consumers to foodborne illness risks : awareness of iraqi consumers to foodborne illness risks . Iraqi Journal of Market Research and Consumer Protection, 15(1): 232–238. doi: http://dx.doi.org/10.28936/jmracpc15.1.2023.(21).
4- Al soufi, M. A. 2022. Iraqi consumer awareness off the risk associated with consuming canned food: Iraqi consumer awareness off the risk associated with consuming canned food, Iraqi Journal of Market Research and Consumer Protection ,(2)14: 83-75. doi: http://dx.doi.org/10.28936/jmracpc14.1.2022.(8).
5- Al soufi, M. A. 2021. Iraqi consumer opinion of the quality and safety of local food products: iraqi consumer opinion of the quality and safety of local food products. Iraqi Journal of Market Research and Consumer Protection, 13(1): 140–147. doi: http://dx.doi.org/10.28936/jmracpc13.1.2021.(14).
6- Alamri, M.S., Akram A.A. Qasem, Abdellatif A. Mohamed, Shahzad Hussain, Mohamed A. Ibraheem, Ghalia Shamlan, Hesham A. Alqah, Ali S. Qasha .2021. Food packaging’s materials: A food safety perspective. Saudi Journal of Biological Sciences, 28 (8): 4490–4499. doi: 10.1016/j.sjbs.2021.04.047.
7-- Bil, W., M. Zeilmaker; S. Fragki; J. Lijzen; E.Verbruggen and B. Bokkers, 2021. Risk assessment of per- and polyfluoroalkyl substance mixtures: A relative potency factor approach. Environmental Toxicology and Chemistry, 40(3): 859–870. doi: 10.1002/etc.4835.
8- Choi, H.; I.-A.Bae,; J.C.Choi; S.-J.Park and M. Kim,.2018.Perfluorinated compounds in food simulants after migration from fluorocarbon resin-coated frying pans, baking utensils, and non-stick baking papers on the korean market. Food Addit. Contam. Part B, 11: 264–272. doi: 10.1080/19393210.2018.1499677.
9- Commission Regulation (EU) .2022. Regards Maximum Levels Of Perfluoroalkyl Substances In Certain Foodstuffs, No. 2022/2388 of 7 December.
10- Elizalde, M.P.; S.Gómez-Lavín and A.M. Urtiaga, 2018. Migration of perfluorinated compounds from paperbag to tenax® and lyophilised milk at different temperatures. Int. J. Environ. Anal. Chem., 98: 1423–1433. doi: 10.1080/03067319.2018.1562062
11- - Fengler, R.; M. Schlummer; L. Gruber; D. Fiedler and N. Weise .2011.Migration of fluorinated telomer alcohols (ftoh) from food contact materials into food at elevated temperatures. Organohalogen Compd. 73: 939–942.
12- Grafia, A.L.; Gonzalez, N.; Pacheco, C.; Razuc, M.F.; Acebal, C.C.; López, O.V. 2025. Eco-Friendly Packaging for Functional Food. Processes, 13, 2027. https://doi.org/10.3390/ pr13072027.
13- Gupta, R.K.; Pipliya, S.; Karunanithi, S.; Eswaran U, G.M.; Kumar, S.; Mandliya, S.; Srivastav, P.P.; Suthar, T.; Shaikh, A.M.; Harsányi, E.; et al.2024. Migration of Chemical Compounds from Packaging Materials into Packaged Foods: Interaction, Mechanism, Assessment, and Regulations. Foods, 13, 3125.https://doi.org/10.3390/foods13193125.
14 - Husain, w. A. and m. A. J. alkhafaji, 2022. The role of commodity dumping in encouraging the iraqi consumer to buy non- essential goods: the role of commodity dumping in encouraging the iraqi consumer to buy non- essential goods. Iraqi Journal of Market Research and Consumer Protection, 14(2): 1–11. doi: http://dx.doi.org/10.28936/jmracpc14.2.2022.(1).
15- - Llorca, M ;M. Farré; M. S. Tavano; B. Alonso; G. Koremblit and D. Barceló. 2012. Fate of a broad spectrum of perfluorinated compounds in soils and biota from Tierra del Fuego and Antarctica. Environ. Pollut. 163: 158–166. doi: 10.1016/j.envpol.2011.10.027.
16- Mkhari, T.; Adeyemi, J.O.;Fawole, O.A. 2025. Recent Advances in the Fabrication of Intelligent Packaging for Food Preservation: A Review.Processes, 13, 539. https://doi.org/10.3390/pr13020539.
17-- Pearson, D. 1976. The Chemical Analysis Of Foods, 7th ed. Churchill Livingstone, Edinburgh, London and New York, U.S.A. pp: 575.
18- Stahl T, D Mattern and H. Brunn .2011. Toxicology of perfluorinated compounds (Review). Environmental Sciences Europe. 23: 1-52. doi:10.1186/2190-4715-23-38.
19- Susmann, H.P.; L.A. Schaider; K.M. Rodgers, and R.A. Rudel, 2019.Dietary habits related to food packaging and population exposure to PFASs. Environ. Health Perspect. 127: 107003. doi: 10.1289/EHP4092.
20- - Teflon. (n.d.). 2021. The History of TeflonTM Fluoropolymers. Retrieved May 14, 2021,pp:1-2,https://www.teflon.com/en/news-events/history.
21- US Environmental Protection Agency.2019. “Pulp and Paper Production (MACT I & II): National Emissions Standards for Hazardous Air Pollutants (NESHAP) for Source Categories.” EPA, January 2017. Retrieved March 7, 2019, from https://www.epa.gov/stationary-sources-air-pollution/pulp-and-paper-production-mact-i-iii-national-emissions standards
22- Zabaleta, I.; N. Negreira; E. Bizkarguenaga; A. Prieto; A. Covaci and O. Zuloaga, 2017.Screening and identification of per- and polyfluoroalkyl substances in microwave popcorn bags. Food Chemistry, 230: 497–506. doi: 10.1016/j.foodchem.2017.03.074.
23- - Zhu, J.; B. Yang; L. Peng; J. Wu; H. Hao and S. Lou, 2023.Target-triggered double fluorescent biosensors for rapid and sensitive detection of long-chain perfluorinated compounds using DNA probe and lysozyme fiber. Sci. Total Environ., 860: 160496. doi: 10.1016/j.scitotenv.2022.160496.
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